Rearrangement of a steroidal 14β-hydroperoxide. Cleavage of ring D
- 15 February 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 48 (4) , 691-693
- https://doi.org/10.1139/v70-113
Abstract
The rearrangement of 14β-hydroperoxy-Δ15-androsten-3β-ol-17-one 3-acetate (2) with boron trifluoride etherate affords 3β,15-dihydroxy-14,15-seco-Δ15-5α-androstene-14,17-dione 3-acetate (4a). The decarbonylation of the rearrangement product was studied.Keywords
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