Regiospecific rearrangements of η2and η4-1,4-diene complexes of iron(0); the mechanisms of metal-promoted 1,3-hydrogen shifts
- 1 January 1975
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 619-620
- https://doi.org/10.1039/c39750000619
Abstract
Thermal rearrangements of η2- and η4-3-methylene-4-vinyldihdrofuran-2(3H)-one complexes of iron(0) yield isomeric 1,3-diene complexes via regiospecific 1,3-hydrogen shifts; the mechanistic implications with respect to metal-promoted olefin isomerisations are discussed.Keywords
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