Interpretation of Ti3+ electron spin resonance spectra in alums
- 1 November 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Physics
- Vol. 48 (21) , 2577-2583
- https://doi.org/10.1139/p70-320
Abstract
It is postulated that Ti3+ exists in 12 differently oriented, but otherwise equivalent, magnetic complexes in CsTi(SO4)2∙12H2O and titanium-doped CsAl(SO4)2∙12H2O alums. This explanation appears to clear up the discrepancy between the theory and the experimental g values found by ESR measurements. The analysis indicates that the titanium ion in alums exhibits a particular class behavior and this is true whether the titanium exists in dilute or concentrated form.Keywords
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