Molecular recognition of carbohydrates by functionalized zinc porphyrins

Abstract
A trifunctional porphyrin host [cis-5,15-bis(8-quinolyl)porphyrinato]zinc 1 exhibits a marked affinity for octyl β-D-glucopyranoside 12 in CHCl3 with an association constant of 41 400 dm3 mol–1; solvent effects on the binding are compared with those for [cis-5,15-bis(2,7-dihydroxy-1-naphthyl)porphyrinato]zinc 3.

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