Organically Templated Mixed-Valent TiIII/TiIV Phosphate with an Octahedral- Tetrahedral Open Framework
- 1 February 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (3) , 372-375
- https://doi.org/10.1002/(sici)1521-3773(19990201)38:3<372::aid-anie372>3.0.co;2-p
Abstract
The first large‐pore, mixed‐valent titanium phosphate was hydrothermally synthesized by using elemental titanium as a starting material, and 1,3‐diaminopropane as a template. The structure displays an open framework containing octahedrally coordinated TiIII and TiIV centers and tetrahedrally coordinated P centers; the diamine molecules are located within the zigzag channels (the picture shows a polyhedral representation of the structure).Keywords
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