Some complexes of Rhodium and Iridium halides with organic sulphides (thioethers)
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 899-904
- https://doi.org/10.1039/j19710000899
Abstract
The reactions of rhodium trichloride with monosulphides give mer-[RhCl3(PhSR)3](R = Me, Et, Prn, or Bun), and fac-[RhCl3(PhSR)3](R = Et, Prn, or Bun). Rhodium(I) sulphide complexes are much more difficult to characterise, and only polymeric materials were isolated. Iridium(I) and iridium(III) have a low affinity for mono- and di-sulphides, and the compounds isolated do not seem to be very like the analogous phosphine complexes.Keywords
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