Calculation of Depolarization Factors of the Raman Lines of CCl3X Molecules
- 1 December 1955
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (12) , 2207-2209
- https://doi.org/10.1063/1.1740724
Abstract
The depolarization factors of the totally symmetric vibrations of CCl3H, CCl3D, and CCl3Br are computed using previously derived expressions for the spur and anisotropy of the polarizability tensor. The associated normal coordinate treatment uses the Wilson FG‐matrix technique with a general quadratic potential function. Calculated and observed depolarization factors agree well for stretching but not for the bending modes.Keywords
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