Crystal Structure and Chemical Reactivity of Heme Phenoxide Adducts
- 1 June 1991
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 23 (1-4) , 351-359
- https://doi.org/10.1080/00958979109408264
Abstract
A simple phenoxide heme compound has been fully structurally characterized for the first time. The crystal structure of a 2,6-dichlorophenoxy Fe(III) 5,10,15,20-tetraphenylporphyrin is reported and compared with the structure of simple aliphatic alkoxy aducts of Fe(III) porphyrins. It is further shown that phenoxy Fe porphyrins can promote regiospecific substitution (cyanation) of the bound phenol ring.Keywords
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