A Note on the Vibrational Frequencies and the Entropy of Decaborane
- 1 November 1952
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 20 (11) , 1749-1751
- https://doi.org/10.1063/1.1700282
Abstract
The infrared spectra of solid decaborane and of decaborane in a solution of carbon disulfide as well as the Raman spectrum of the solution have been recorded. A rough selection of fundamental frequencies is made; this, together with the molecular parameters from x‐ray data, is used for calculating S298.160 of the gas, for which a value of 83.85 eu is obtained. This figure compares with that derived from thermodynamic measurements, namely, 87.36 eu.Keywords
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