Fine Structure in Energy Spectra of Ultrasmall Au Nanoparticles

  • 25 October 1999
Abstract
We have measured the electronic energy spectra of Au nanoparticles of diameter 2-5 nm by tunnel spectroscopy, and found that the electron-in-a-box levels can be split into 2-10 energy levels, even in zero magnetic field. We propose that this splitting may result from spin multiplets in the presence of strong spin-orbit interaction. Relation to a theoretical model is discussed.

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