Synthetic Studies on the Validamycins. VII. Synthesis of Dl-2-Deoxyhydroxyvalidamine and Dl-2-Deoxyvalienamine

Abstract
Synthesis of the 2-deoxy analogs of DL-hydroxyvalidamine and DL-valienamine starting from DL-1,2-di-O-acetyl-(1,3,5/2)-5-bromo-3-bromomethyl-1,2-cyclohexanediol is described.