The mass spectrometry of nitrate esters and related compounds. Part I
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 659-663
- https://doi.org/10.1039/j29680000659
Abstract
The mass spectra of 31 nitrate esters have been measured. The compounds fragment in a manner dependent on the number and nature (O·NO2 or OH) of substituents present. Appearance potential measurements yield a value of 7·5 ± 0·2 eV for the ionization potential of the nitro-oxymethyl group, CH2·O·NO2.Keywords
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