SYNTHESIS OF OPTICALLY ACTIVE SELENOXIDE
- 5 February 1986
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 15 (2) , 161-164
- https://doi.org/10.1246/cl.1986.161
Abstract
Fractional recrystallization of diastereomeric 2,4,6-triisopropylpheny1 4′-(l-menthyloxycarbonyl)phenyl selenoxide gave optically pure (−)-selenoxide. Transesterification of this diastereomerically pure (−)-selenoxide with methanol gave enantiomeric (−)-2,4,6-triisopropylphenyl 4-′-(methoxycarbonyl)phenyl selenoxide in 88.1% optical purity.This publication has 2 references indexed in Scilit:
- First synthesis of simple optically active selenoxidesTetrahedron Letters, 1983
- Neurotropic and psychotropic substances. XXXVII. Derivatives of selenoxantheneCollection of Czechoslovak Chemical Communications, 1969