Universality Class of Criticality in the Restricted Primitive Model Electrolyte
- 18 April 2002
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 88 (18) , 185701
- https://doi.org/10.1103/physrevlett.88.185701
Abstract
The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using loci in the temperature-density or plane of isothermal vs pressure inflections, of maxima, and of canonical and criticality, yield estimates of to . Extrapolated exponents and ratio are , which support Ising behavior with , but exclude classical, , self-avoiding walk , and criticality with potentials when .
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