Universality Class of Criticality in the Restricted Primitive Model Electrolyte

Abstract
The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using loci in the temperature-density or (T,ρ) plane of isothermal ρ2k vs pressure inflections, of Qm22/m4 maxima, and of canonical and CV criticality, yield estimates of (Tc,ρc) to ±(0.04,3)%. Extrapolated exponents and Q ratio are (γ,ν,Qc)=[1.24(3),0.63(3);0.624(2)], which support Ising (n=1) behavior with (1.239,0.6303;0.6236), but exclude classical, XY (n=2), self-avoiding walk (n=0), and n=1 criticality with potentials ϕ(r)>Φ/r4.9 when r.
All Related Versions

This publication has 31 references indexed in Scilit: