Some problems associated with the application of thermal methods to polymers

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Abstract
The scope of thermal methods and their application to polymeric substrates are reviewed. The general application of these methods to polymers is discussed and illustrated by reference to: (i) the problems associated with thermal methods and the apparatus used to obtain thermal responses; (ii) the problems associated with calibration and the standardisation of reporting procedures; (iii) the specific problems associated with polymeric materials. Problems associated with crystallinity determinations and thermal stability assessment are also discussed.