Competitive substitution and fragmentation reactions of cation radicals derived from adamantanes
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 816-817
- https://doi.org/10.1039/c39750000816
Abstract
1-Alkyladamantanes undergo anodic oxidation in dry acetonitrile to give 3-alkyl-1-adamantyl acetamides and anodic fragmentation to give 1-adamantylacetamide; fragmentation is favoured by loss of a tertiary fragment but is not sensitive to temperature change.Keywords
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