Assessment of oxygen in gallium arsenide by infrared local vibrational mode spectroscopy

Abstract
Two infrared local vibrational mode (LVM) absorption lines occurring at 715 and 845 cm1 shift to 679 and 802 cm1 in gallium arsenide doped with 18O, proving that the lines arise from the vibrations of oxygen impurities. The 715 cm1 line exhibits a triplet 69,71Ga isotope fine structure consistent with that expected from a quasi‐substitional VAs‐O center. The 845 cm1 line appears as a closely spaced doublet expected for a bonded interstitial oxygen atom.

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