Activation and functionalisation of the C–H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 991-992
- https://doi.org/10.1039/c39950000991
Abstract
Silica-supported tantalum hydride activates at low temperature the C–H and the C–D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.Keywords
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