Synthesis and chiral recognition of an optically active bis-crown ether incorporating a diphenanthrylnaphthalene moiety as the chiral centre
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 168-169
- https://doi.org/10.1039/c39870000168
Abstract
A novel optically active double-layered bis-crown ether (–)-(S,S)-(7) with a diphenanthrylnaphthalene moiety as the chiral centre has been prepared, and examination of its chiral recognition behaviour showed that (–)-(S,S)-(7) has a high enantiomer selectivity for 1,6-diphenylhexamethylene-1,6-diamine.Keywords
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