Kinetics of hydrogenation of cyclic butadiene oligomers on palladium catalysts. Cyclooctadiene isomers
- 1 January 1981
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 46 (4) , 1031-1038
- https://doi.org/10.1135/cccc19811031
Abstract
Kinetics of hydrogenation of 1,3- and 1,5-cyclooctadiene and cyclooctene on palladium support catalysts (Pd/CaCO3, Pd/γ-Al2O3) were measured in heptane solutions at 300 K and atmospheric pressure of hydrogen. The kinetic constants were obtained by relating the experimental data to a kinetic model in which the partial reactions are assumed to be 1 st order.Keywords
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