Tin complexes containing the nitrate group: crystal structure of polymeric (2-aminobenzothiazolato)nitratotin(II)
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 15,p. 1595-1597
- https://doi.org/10.1039/dt9750001595
Abstract
The structure of the title compound was solved from X-ray diffractometer data by Patterson and Fourier methods and refined by least-squares techniques to R 5.9% for 2 166 independent reflections. Crystals are monoclinic, space group P21/c, with unit-cell dimensions: a= 9.993(5), b= 6.915(4), c= 13.593(6)Å. β= 91.9(1)°, Z= 4. Co-ordination around tin can be described as tetrahedral and involves two adjacent NO3 – anions and two organic molecules. There are two longer Sn-O contacts which complete the co-ordination to six. The nitrate group and the organic ligand both bridge two metal atoms in a rather unusual way, causing the structure to be polymeric.Keywords
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