Application of thermogravimetric techniques to reaction kinetics
- 1 December 1965
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A: General Papers
- Vol. 3 (12) , 4253-4262
- https://doi.org/10.1002/pol.1965.100031221
Abstract
An easier technique for the determination of reaction constants such as order, energy of activation, and frequency factor from the thermogravimetric data has been described. The method requires two TGA curves obtained with different sample weights under similar reaction conditions. Applicability of the method to complex reactions, where simultaneous decomposition occurs, has been discussed. Reaction constants for different steps of the decomposition of calcium oxalate monohydrate are evaluated.Keywords
This publication has 8 references indexed in Scilit:
- A graphical estimation of reaction order from thermogravimetric tracesJournal of Polymer Science Part B: Polymer Letters, 1964
- A rapid estimation of activation energy from thermogravimetric tracesJournal of Polymer Science Part B: Polymer Letters, 1964
- Note on the thermal degradation of teflonJournal of Polymer Science Part B: Polymer Letters, 1963
- Kinetic analysis of thermogravimetric dataJournal of Applied Polymer Science, 1961
- The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate MonohydrateThe Journal of Physical Chemistry, 1958
- The calcination of dolomite. Part I.—The kinetics of the thermal decomposition of calcite and of magnesiteTransactions of the Faraday Society, 1952
- Die Kinetik des thermischen Zerfalls von CalciumcarbonatAngewandte Chemie, 1940
- A stathmographic and kinetic investigation of the thermal decomposition of lime-stoneCollection of Czechoslovak Chemical Communications, 1937