Boron Trifluoride-Assisted Reaction of Perfluoroalkyllithiums with Imines. A Novel Route to Perfluoroalkylated Amines
- 5 April 1988
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (4) , 729-732
- https://doi.org/10.1246/cl.1988.729
Abstract
In the presence of BF3, perfluoroalkyllithiums were found to react with imines to give perfluoroalkylated amines in moderate to good yields.This publication has 12 references indexed in Scilit:
- Nucleophilic addition of the pentafluoroethyl group to aldehydes, ketones, and estersThe Journal of Organic Chemistry, 1987
- Synthetic and mechanistic studies involving the condensation of penicillin grignards and boron trifluoride activated oxime ethersTetrahedron Letters, 1986
- Ultrasound-promoted selective perfluoroalkylation on the desired position of organic moleculesJournal of the American Chemical Society, 1985
- Addition of alkynyl anions to aldimines containing α-hydrogens: a novel synthesis of β-aminoacetylenesTetrahedron Letters, 1984
- Addition of boron trifluoride complexes of organocopper reagentsto aldimines containing α-hydrogensTetrahedron Letters, 1984
- 2. Boron trifluoride activated 3-thiazolines. A versatile synthesis of thiophenesTetrahedron Letters, 1983
- 1. Boron trifluoride activaed 3-thiazolines. An efficient preparation of functionalized thiazolidines.Tetrahedron Letters, 1983
- Addition of boron enolates to isoquinolinium salts: A facile synthesis of 1-β-keto substituted 2-ethoxycarbonyl-1,2-dihydroisoquinolines and their cyclizationTetrahedron Letters, 1981
- Syntheses via-2-oxazolines. I. Formylation of Grignard reagents in the presence of hexamethylphosphoramideJournal of the American Chemical Society, 1970
- Reactions of Polyfluoro Olefins. II.1 Reactions with Primary and Secondary Amines2Journal of the American Chemical Society, 1950