Solid-state studies. Part II. Raman- and infrared-active carbonyl stretching vibrations of four methylbenzenetricarbonylchromium complexes
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2224-2227
- https://doi.org/10.1039/j19690002224
Abstract
The solid-state Raman- and i.r.-active carbonyl stretching vibrations of hexamethyl-, pentamethyl-, 1,2-dimethyl-, and methyl-benzenetricarbonylchromium are discussed in terms of a vibrational factor-group which is different from the crystallographic factor-group. All the spectra may be considered, in first-order approximation, as arising in band sets from the carbonyl stretching vibrations of the molecule in dilute solution.Keywords
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