Mössbauer Studies of Ferro- and Ferricyanide Supercomplexes with 3d Transition Elements
- 15 February 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (4) , 1466-1468
- https://doi.org/10.1063/1.1840875
Abstract
The results of systematic Mössbauer studies of the ferro- and ferricyanide supercomplexes with 3d transition elements (Cr, Mn, Fe, Co, Ni, Cu, and Zn) are reported. It is concluded that the coordination number of Fe(II) remains six, and a metal—metal charge transfer is invoked to explain the data. The nearly double values of quadrupole splittings in ferricyanide supercomplexes, as compared to K3Fe(III) (CN)6 are explained.Keywords
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