New arrangements of transition metal atoms in carbido-carbonyl clusters of rhodium and cobalt
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 299-300
- https://doi.org/10.1039/c39740000299
Abstract
New carbido-carbonyl cluster compounds of rhodium have been isolated and two of them, characterized by crystallographic methods, have been formulated as Rh8(CO)19C and [H3O][Rh15(CO)28C2]; the synthesis of carbido-carbonyl clusters has been extended to cobalt for which the anion [Co6(CO)15C]2– has been obtained.Keywords
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