Molecular polarisability. Anisotropies of silicon containing groups
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 77 (1) , 55-60
- https://doi.org/10.1039/f29817700055
Abstract
Electric dipole moments and molar Kerr constants of nine organosilicon compounds examined as solutes are analysed to derive component group polarisabilities. The polarisability tensor is specified for Si–Me, Si–H, Si–F, Si–Cl, Si–O and Si–N. A “valence-optical scheme” appears valid for this series of compounds.Keywords
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