Novel low-temperature route to known (MnS and FeS2) and new (CrS3, MoS4 and WS5) transition-metal sulfides
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 2 (8) , 895-896
- https://doi.org/10.1039/jm9920200895
Abstract
The reaction of the transition-metal carbonyls, Mn2(CO)10, Fe(CO)5 or M(CO)6(M = Cr, Mo or W) with sulfur in 1, 2-dichlorobenzene yields polycrystalline MnS (alabandite), FeS2(marcarsite), and three new amorphous sulfur-rich sulfides CrS3, MoS4 and WS5.Keywords
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