Isolation and crystal and molecular structure of a rare example of a mononuclear organo-cuprate
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 240-241
- https://doi.org/10.1039/c39830000240
Abstract
The reaction of mesitylcopper(I), CuAr, with 1,2-bis (diphenylphosphino)ethane, dppe, gives [(dppe)2Cu2Ar2], whose molecular structure, determined by a single-crystal X-ray study, consist of a linear mononuclear [CuAr2]– unit with a tetrahedral [Cu(dppe)2]+ unit as counter-ion.Keywords
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