Isolation of a new intermediate complex in the nitrogen-fixing system (π-C5H5)2TiCl + MeMgI + N2
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1178a
- https://doi.org/10.1039/c3972001178a
Abstract
A binuclear complex cp2TiN2Ticp2 has been isolated at low temperature in the system cp2TiCI + MeMgI + N2(cp =π-C5H5); it is apparently a di-imide derivative, and initially froms N2H2 when decomposed with HCl.Keywords
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