U–Pb isotopic dating of fluid infiltration and metasomatism during Dalradian regional metamorphism in Connemara, western Ireland

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Abstract
A metasomatic diopside rock occurs at the top of the dolomitic Connemara Marble Formation of western Ireland and contains titanite and K‐feldspar in addition to around 90% diopside (XMg= 0.90–0.97). U–Pb isotopic measurements on this mineral assemblage show that the titanite is both unusually uranium‐rich and isotopically concordant, with the result that a precise U–Pb age of 478 ± 2.5 Ma can be determined. The age is identical within error to a less precise Rb–Sr age of diopside–K‐feldspar of 483 ± 6 Ma. Petrological evidence indicates that the assemblage crystallized at c. 620° C close to or below the closure temperature of titanite. The age thus provides a precise estimate of the time of metamorphism; this age is 11 ± 3 Ma younger than the 490 Ma age for nearby gabbroic plutons which has previously been used to constrain the peak metamorphic age. This difference accords well with geological evidence that the gabbros were emplaced prior to the metamorphic peak. Analysis of minerals with high closure temperature from assemblages whose crystallization is unambiguously associated with a specific episode of fluid infiltration at the peak of metamorphism provides the basis for a new approach to dating metamorphism. The success of this approach is demonstrated by the results from Connemara.