Useful Syntheses of (3S)-2,3,4,5-Tetrahydropyridazine-3-carboxylic Acid and Its Dehydrotetrapeptide Derivatives

Abstract
The stereoselective synthesis of (3S)-2,3,4,5-tetrahydropyridazine-3-carboxylic acid (Pya), which is a cyclic α-amino acid at center of antrimycins (1), was successful. Moreover, the synthesis of the C-terminal dehydrotetrapeptide of 1 containing Pya residue at N-terminus is described.

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