Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniquesElectronic supplementary information (ESI) available: EXAFS data and Fourier Transform. See http://www.rsc.org/suppdata/cc/b2/b206758g/

Abstract
UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.

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