KINETICS AND THERMODYNAMICS OF THE CRYSTAL STRUCTURE TRANSFORMATION OF SPECTROSCOPICALLY PURE ANATASE TO RUTILE

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Abstract
The transformation of spectroscopically pure anatase to rutile was first investigated by Czanderna, Rao, and Honig. But it was not possible, then, to provide the mechanism on a molecular scale because of the lack of very accurate kinetic data. The kinetics and thermodynamics of the transformation have now been carefully investigated.

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