Dissociation Constants of Ethane-1-hydroxy-1,1-diphosphonate [EHDP] and Dichloromethylene-diphosphonate [Cl2MDP] for H+, Ca2+, Mg2+ and Zn2+

Abstract
The diphosphonates EHDP and Cl2MDP have been used for studying bone metabolism and for treatment of bone diseases. The Kd of EHDP and Cl2MDP for H+, Ca2+, Mg2+ and Zn2+ were determined from pH titration curves. EHDP forms more stable chelates with Ca2+, Mg2+ and Zn2+ than Cl2MDP. CL2MDP is a stronger acid than EHDP.

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