The backbone rearrangement of des-A-steroids: some mechanistic aspects
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1162-1163
- https://doi.org/10.1039/c29700001162
Abstract
Using deuteriated substrate and reagent, it was shown that the backbone rearrangement of des-A-steroidal hydroxy-olefins does not proceed through protonation–deprotonation of intermediate olefins or cyclopropanes.Keywords
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