Glass‐Forming Region and Structure of Oxyhalide Glasses in the System LiCl‐Li2O‐TeO2

Abstract
The glass‐forming region for oxyhalide glasses in the system LiCl‐Li2O‐TeO2 has been established. It extends to the LiCl‐rich side, ranging from 15 to 60 mol% LiCl, whereas it is limited to only about 30 mol% Li2O on the lithia‐rich side. The reason for such an extended glass‐forming region on addition of LiCl to TeO2 is discussed on the basis of the results of infrared spectroscopic measurements.

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