Do radical and ionic pathways of decomposition of arenediazonium ions in acidic methanol proceed via a common intermediate?
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1363-1364
- https://doi.org/10.1039/c29700001363
Abstract
In acidic methanol, arenediazonium ions de-compose either by a radical mechanism, forming ArH, or by an ionic mechanism to form ArOMe; in some cases the former pathway predominates under N2 and the latter under O2, but the rates are sufficiently similar to suggest that perhaps both proceed via a common intermediate.Keywords
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