Facile Preparation of Fluorine-containing Alkenes, Amides and Alcohols via the Electrophilic Fluorination of Alkenyl Boronic Acids and Trifluoroborates
- 1 May 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (5) , 606-608
- https://doi.org/10.1055/s-1997-3228
Abstract
Reaction of alkenyl boronic acids, or preferably alkenyl trifluoroborates, with one equivalent of SelectfluorTM gives the corresponding alkenyl fluorides. A similar reaction with two equivalents of SelectfluorTM in water or a nitrile solvent gives difluoromethyl-substituted alcohols and amides respectively.Keywords
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