cis-Dioxo- and trioxo-complexes
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 400-404
- https://doi.org/10.1039/j19680000400
Abstract
Raman and infrared spectra have been measured of a number of transition-metal complexes of the form [MO2X4]n–(M = MoVI, WVI, or VV; X = F, Cl, or ½ Ox), and a cis configuration of the oxygen ligands has been found for these d0-species. The results are compared with those obtained for trans-dioxo-complexes and the dífferences explained in terms of the oxygen–metal bonding involved. The vibrational spectra of a number of trioxo-species and some polymeric oxyfluorides have also been measured.Keywords
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