Some Aspects of the Reaction between Chitosan and Formaldehyde

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Abstract
Reactions of chitosan (degree of deacetylation 67%, weight-average molecular weight 850,000) with formaldehyde were performed in a dilute aqueous acetic acid solution at a molar ratio of amino groups of the polymer to HCHO of 0.06:O.1 mol/L and at different temperatures (45, 60, and 75°C). In each case the pH of the reaction mixtures was 3.4 during the experiments. The process was investigated by measuring the kinetic changes of the free formaldehyde concentration and the sum of free formaldehyde and methylol groups produced. No gelation of the reaction product was observed. The experimental results led to the conclusion that the methylol groups formed by the addition of HCHO to chitosan functions take part in some intramolecular reactions with amino and/or hydroxyl groups of chitosan. Initially, the concentration of the resultant methylene bridges grows rapidly and then drops again until an equilibrium is established. This rather unusual decomposition of the methylene links once formed without changing the reaction conditions is accompanied by a substantial growth of the amount of methylol derivative whose concentration at the beginning of the process increased rather slowly.

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