Kristall- und Molekülstruktur vonbis-Methallylnickel Ni[(CH2)2C · CH3]2
- 1 October 1965
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Kristallographie
- Vol. 122 (1-2) , 60-72
- https://doi.org/10.1524/zkri.1965.122.1-2.60
Abstract
The crystal structure of bis -methallylnickel has been determined from three-dimensional x-ray diffraction data. The space group is P 2 1 / c − C 2 h 5 , with a = 6.05; b = 13,48; c = 5.83 Å; β = 117.1°. The unit cell contains 2 molecules with Ni in centres of symmetry. The methallyl groups are symmetrically bonded to the nickel in an anti-sandwich arrangement. This causes the intramolecular symmetry to be 2/ m . The methallyl groups are found to be nonplanar and the Ni–C bonds are quite short (average 2.02 Å).This publication has 4 references indexed in Scilit:
- Die Kristallstruktur vonbis-Cyclooctadien-(1,5)-Nickel(0)Zeitschrift für Kristallographie, 1965
- Cyclooligomerisation von Butadien und Übergangsmetall‐π‐KomplexeAngewandte Chemie, 1963
- Zur Kristallstruktur von BismethallylnickelThe Science of Nature, 1963
- New calculations of atomic scattering factorsActa Crystallographica, 1955