An Essentially Mild and Efficient Catalyst System for the Activation of Carbonyl Compounds and Their Derivatives. The Combined Use of Trimethylsilyl Chloride and Tin(II) Chloride
- 5 March 1987
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 16 (3) , 463-466
- https://doi.org/10.1246/cl.1987.463
Abstract
An essentially mild and efficient catalyst system, the combined use of trimethylsilyl chloride and tin(II) chloride, is effectively employed for the activation of acetals, aldehydes, orthoesters, and α,β-unsaturated ketones to accomplish the reaction with silyl enol ethers to give the corresponding addition products in good yields.Keywords
This publication has 4 references indexed in Scilit:
- Catalytic homo-Reformatskii reaction. Ambident chemical reactivities of the zinc homoenolate of propionateThe Journal of Organic Chemistry, 1985
- Trimethysilyl triflate in organic synthesis11Part 11 of this series. Part 10: S. Murata and R. Noyori, Tetrahedron Letters 2107 (1981).Tetrahedron, 1981
- Regiospecific allylation of acetals with allylsilanes catalyzed by iodotrimethylsilane. Synthesis of homoallylethersTetrahedron Letters, 1981
- Useful diene for the Diels-Alder reactionJournal of the American Chemical Society, 1974