Theory of alternating current polarography. I. Equation of the reversible AC polarographic wave
- 1 January 1954
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 7 (3) , 225-238
- https://doi.org/10.1071/ch9540225
Abstract
An equation for the A.C. polarographic current is derived from considerations of concentration changes produced at the dropping mercury electrode in virtue of the superposition of a small sinusoidal alternating voltage onto the direct potential, for the case of reversibly reduced inorganic ions. The equation predicts the magnitude of the A.C. polarographic current at any point on the polarogram.Keywords
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