Substituent Effects in Gas-Phase Substitutions and Eliminations: β-Halo Substituents. Solvation Reverses SN2 Substituent Effects
- 8 March 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 123 (13) , 3081-3091
- https://doi.org/10.1021/ja003955q
Abstract
No abstract availableThis publication has 45 references indexed in Scilit:
- Kinetics of the gas-phase reactions of chloride anion, Cl- with CH3Br and CD3Br: experimental evidence for nonstatistical behavior?Journal of the American Chemical Society, 1992
- A survey of Hammett substituent constants and resonance and field parametersChemical Reviews, 1991
- Quantitative proton affinities, ionization potentials, and hydrogen affinities of alkylaminesJournal of the American Chemical Society, 1976
- Effects on reactivity in E1cB reactionsJournal of the American Chemical Society, 1968
- Kinetic Studies of Bimolecular Nucleophilic Substitution. IV. Rates of the SN2 and E2 Reactions of β-Substituted Ethyl Chlorides with Sodium Acetate in Aqueous SolutionsBulletin of the Chemical Society of Japan, 1967
- The Effect of Halogen Atoms on the Reactivity of Other Halogen Atoms in the Same Molecule. VII. The Reaction of β-Haloethyl Bromides with Sodium Hydroxide1Journal of the American Chemical Society, 1956
- The Solvolysis and Base-catalyzed Dehydrohalogenation of 1,1- and 1,2-Dihalocyclohexanes1Journal of the American Chemical Society, 1956
- The Iodide Ion Exchange Reaction with 2-Haloethyl Alkyl Ethers and n-Butyl Bromide1Journal of the American Chemical Society, 1954
- A Reëxamination of the Hammett Equation.Chemical Reviews, 1953
- The Effect of Halogen Atoms on the Reactivity of Other Halogen Atoms in the Same Molecule. III. The SN2 Reactivity of Ethylene Halides1Journal of the American Chemical Society, 1953