Use of phospha-alkynes in metal aggregate synthesis. Crystal and molecular structure of the remarkable hexa-rhodium complex [Rh₂Cl₂{Rh(η⁵-C₅H₅)(P₂C₂Bu^t₂)}₄]

1 January 1987

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 11,p. 844-845
https://doi.org/10.1039/c39870000844

Abstract

The remarkable hexa-rhodium compound [Rh₂Cl₂{Rh(η⁵-C₅H₅)(P₂C₂Bu^t ₂)}₄] is obtained from the 1,3-diphosphacyclobutadiene complex [Rh(η⁵-C₅H₅)(P₂C₂Bu^t ₂)] and [RhCl(C₂H₄)₂]₂.

Keywords

MOLECULAR STRUCTURE

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Use of phospha-alkynes in metal aggregate synthesis. Crystal and molecular structure of the remarkable hexa-rhodium complex [Rh2Cl2{Rh(η5-C5H5)(P2C2But2)}4]

Abstract

Keywords

Use of phospha-alkynes in metal aggregate synthesis. Crystal and molecular structure of the remarkable hexa-rhodium complex [Rh₂Cl₂{Rh(η⁵-C₅H₅)(P₂C₂Bu^t₂)}₄]