Electron Resonance Powder Spectra for Systems with S > 12
- 15 January 1970
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 52 (2) , 535-538
- https://doi.org/10.1063/1.1673018
Abstract
A qualitative interpretation, ignoring nuclear hyperfine effects, of the line shapes and positions of all the lines occurring in the ESR powder spectra for S = 32, 52 systems with rhombic environments is presented. The formulation of the problem assumes the zero-field tensor is dominant in determining the angular dependence of oriented crystal spectra. In favorable cases, g factors and zero-field splitting parameters can be determined, and results from powder spectra are compared with spin-Hamiltonian parameters obtained from a single crystal study of Cr3+: (NH4)2[In(H2O)Cl5].Keywords
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