Reactions of gold–phosphine cluster compounds
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 907-909
- https://doi.org/10.1039/c39780000907
Abstract
[Au9L8]3+(L = PPh3) reacts with L to give [Au9L10]3+ and with X–(X = Cl, Br, I, CN, or SCN) to give Au9L8X3 which converts into [Au11L8X2]+ in solution (investigated for X = Cl and SCN); from 31P [1H] n.m.r., i.r., and Mössbauer spectra it is concluded that these new Au9 and Au11 clusters are structurally related to the known complexes [Au9L8]3+ and Au11L7X3, respectively.Keywords
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