Intrinsic Rate Constants for Proton Transfer from a Monoketone to Amine Bases and Electrostatic Effects on the Intrinsic Rate Constants for the Deprotonation of Cationic Ketones by OH-
- 11 February 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 121 (8) , 1674-1680
- https://doi.org/10.1021/ja983304i
Abstract
No abstract availableKeywords
This publication has 24 references indexed in Scilit:
- Intrinsic Barriers and Transition State Structures in the Gas Phase Carbon-to-Carbon Identity Proton Transfers from Nitromethane to Nitromethide Anion and from Protonated Nitromethane toaci-Nitromethane. Anab InitioStudyJournal of the American Chemical Society, 1997
- The low intrinsic reactivity of picrylacetone: an index for the π-acceptor capability of a 2,4,6-trinitrophenyl structureJournal of the Chemical Society, Perkin Transactions 2, 1996
- Electrostatic Acceleration of Enolization in Cationic KetonesJournal of the American Chemical Society, 1996
- Electrostatic stabilization can explain the unexpected acidity of carbon acids in enzyme-catalyzed reactionsJournal of the American Chemical Society, 1993
- A survey of Hammett substituent constants and resonance and field parametersChemical Reviews, 1991
- Kinetics and mechanism of enolization and ketonizationPublished by Wiley ,1990
- A systematic entropy relationship for the general-base catalysis of the deprotonation of a carbon acid. A quantitative probe of transition-state solvationJournal of the American Chemical Society, 1990
- Kinetics of ionization of nitromethane and phenylnitromethane by amines and carboxylate ions in Me2SO-water mixtures. Evidence of ammonium ion-nitronate ion hydrogen bonded complex formation in Me2SO-rich solvent mixturesThe Journal of Organic Chemistry, 1988
- Free energies of transfer of carbon acids and their conjugate carbanions from water to dimethyl sulfoxide-water mixturesJournal of the American Chemical Society, 1988
- Kinetics of the metal ion catalyzed iodination of 2-acetylpyridineJournal of the American Chemical Society, 1974