Diffusion of camphorquinone in uniaxially drawn polycarbonate films

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Abstract
Employing the laser‐induced holographic grating relaxation technique, we have measured tracer diffusion coefficients of a phtochromous dye, camphorquinone, in uniaxially drawn polycarbonate films as a function of stretch ratio. Anisotropy in the tracer diffusion coefficient has been observed with D∥ greater than D⟂ by at least a factor of 4 for the film stretched to the stretch ratio δ = 2.3. The diffusion coefficient along the direction of stretch D∥ increases significantly with increasing δ, whereas D⟂ decreases slightly with increasing δ. The stretch ratio dependence of D∥ and D⟂ is interpreted according to a modified free volume theory. The strain rate and stretch temperature dependence of the anisotropic tracer diffusion coefficient has also been investigated. © 1992 John Wiley & Sons, Inc.